Think Your Skin’s Too Sensitive for Acids? May We Suggest PHAs?
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If you’re at all familiar with the skin-care world, you’ve already heard ofAHAs (alpha hydroxy acids) and BHAs (beta hydroxy acids). These chemical exfoliants promote cellular turnover and can help address a variety of skin concerns, fromacnetoaging. But lately, a new category of exfoliant ingredient — polyhydroxy acids, or PHAs — has become more prevalent, appearing in serums and tonersfrom a range of brandsincludingMARA,Glow Recipe, andByoma.
“PHAs have been around for a long time. They just hadn’t been as common or as popular,” says board-certified dermatologistDr. Wallace Nozile. The most well-known PHAs include gluconolactone, galactose, and lactobionic acid — so if you see PHAs mentioned on a product label, you’ll likely find one of those terms in the ingredients list.
But what do they actually do? I asked dermatologists to explain how PHAs work, what benefits they have to offer, and what skin types they’re best suited for.
PHAs exfoliate more gently — and are less drying — than AHAs and BHAs
PHAs are similar to AHAs and BHAs in that they also help remove dead skin cells from the surface of the skin. But their molecular structure is larger, so they penetrate the skin more slowly and tend to be gentler than many traditional acids, explains board-certified dermatologist and Dermworks founderDr. Jenna Queller.
According to Dr. Queller, AHAs, such as glycolic and lactic acids, primarilyexfoliatethe surface of the skin and are often used to treat concerns like dullness, uneven texture, and fine lines. BHAs, like salicylic acid, are oil-soluble and penetrate deeper into the skin, which makes them helpful for treating acne and clearing clogged pores.
PHAs are closer to AHAs in that they also tend to provide more surface-level exfoliation. But because they penetrate more slowly and even more shallowly than AHAs, they typically cause less irritation and are often better tolerated by people with sensitive skin. Their gentle exfoliation can help improve skin texture, brightness, and overall tone. And while other acids may cause excessive dryness, PHAs tend to have humectant properties, which means they help attract and retain moisture in the skin.
“They’re a lot more hydrating than alpha hydroxy acids or beta hydroxy acids,” says Dr. Nozile, adding they can even helpstrengthen skin-barrier function. Some PHAs have also displayed antioxidant properties, which prevent free-radical damage to the skin caused by environmental stressors like pollution and UV radiation.
PHAs are best for sensitive skin
“PHAs are a great option for people who want the glow of exfoliating acids but don’t tolerate the irritation that can come with stronger acids,” says Dr. Queller. She often recommends them for patients who have conditions likerosaceaor patients with sensitive or reactive skin who have tried stronger exfoliants but found that they caused too much stinging and irritation.
They may also be a good fit for those who are new to the world of chemical exfoliants, helping “bridge them over to where they condition their skin to tolerate stronger active ingredients,” says Dr. Nozile.
Some products with PHAs that dermatologists recommend
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Both Dr. Queller and Dr. Nozile mentioned the brand NeoStrata, which helped pioneer many PHA formulations currently on the market. This gentle gel face wash contains 4 percent gluconolactone and effectivelyremoves makeupand impurities while brightening and refining the skin’s appearance.
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Dr. Nozile says he often recommends the Inkey List’s affordable and accessible products to his clients. This PHA toner also contains niacinamide to control excess oil and redness; it is meant to be swiped on with a cotton pad beforemoisturizerandSPF.
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Strategist writerArielle Avilanamed Eadem’s Cashmere Peel toner thebest gentle exfoliating toner. Even though it contains a blend of AHAs and PHAs, it didn’t give her the tingling sensation that she often feels after using stronger exfoliators. “It has a milkier texture and leaves my skin feeling moisturized instead of dried out,” she writes.
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